J- vs. H-type assembly: pentamethine cyanine (Cy5) as a near-IR chiroptical reporter.

نویسندگان

  • Larysa I Markova
  • Vladimir L Malinovskii
  • Leonid D Patsenker
  • Robert Häner
چکیده

The DNA-enabled dimerization of pentamethine cyanine (Cy5) dyes was studied by optical methods. The value of cyanine as a chiroptical reporter using a monomer-to-dimer switch is demonstrated. The specific shape of the CD signal and its high intensity are a result of J-type assembly.

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عنوان ژورنال:
  • Chemical communications

دوره 49 46  شماره 

صفحات  -

تاریخ انتشار 2013